Thermodynamic Stability Versus Kinetic Lability of ZnS4Core
نویسندگان
چکیده
منابع مشابه
Thermodynamic stability versus kinetic lability of ZnS4 core.
Density Functional Theory and post-Hartree Fock calculations reveal an unusual energy profile for Zn-S and Zn-N bond dissociation reactions in several [Zn(SR)(4)](2-) and [Zn(Im)(SR)(3)](-) complexes. The Zn-S bond dissociation in tetrathiolate dianions, which is highly exothermic in the gas phase, proceeds through a late transition state which can be rationalized on the basis of an avoided cro...
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ژورنال
عنوان ژورنال: Chemistry - An Asian Journal
سال: 2008
ISSN: 1861-4728,1861-471X
DOI: 10.1002/asia.200900624